Pastor Maldonado a créé une immense surprise en remportant le Grand Prix d'Espagne, devant Fernando Alonso, Kimi Räikkönen et Romain Grosjean.
Pastor Maldonado est en pole après la pénalité de Lewis Hamilton, devant Fernando Alonso, Romain Grosjean, Kimi Räikkönen, Sergio Pérez, Nico Rosberg, Sebastian Vettel, Michael Schumacher, Kamui Kobayashi, Jenson Button et Mark Webber. Jean-Eric Vergne est 14ème et Charles Pic 20ème.
Résultat du GP:
| Pos | Pilotes | Ecuries | Ecart | Points |
| 01 | P. Maldonado | Williams | Vainqueur | 25 |
| 02 | F. Alonso | Ferrari | +3.1 secs | 18 |
| 03 | K. Räikkönen | Lotus | +3.8 secs | 15 |
| 04 | R. Grosjean | Lotus | +14.7 secs | 12 |
| 05 | K. Kobayashi | Sauber | +64.6 secs | 10 |
| 06 | S. Vettel | Red Bull | +67.5 secs | 8 |
| 07 | N. Rosberg | Mercedes | +77.9 secs | 6 |
| 08 | L. Hamilton | McLaren | +78.1 secs | 4 |
| 09 | J. Button | McLaren | +1 tour | 2 |
| 10 | N. Hülkenberg | Force India | +1 tour | 1 |
| 11 | M. Webber | Red Bull | +1 tour | |
| 12 | J. Vergne | Toro Rosso | +1 tour | |
| 13 | D. Ricciardo | Toro Rosso | +1 tour | |
| 14 | P. Di Resta | Force India | +1 tour | |
| 15 | F. Massa | Ferrari | +1 tour | |
| 16 | H. Kovalainen | Caterham | +1 tour | |
| 17 | V. Petrov | Caterham | +1 tour | |
| 18 | T. Glock | Marussia | +2 tours | |
| 19 | P. de la Rosa | HRT | +3 tours | |
| Out | S. Perez | Sauber | +29 tours | |
| Out | C. Pic | Marussia | +31 tours | |
| Out | N. Karthikeyan | HRT | +44 tours | |
| Out | B. Senna | Williams | +54 tours | |
| Out | M. Schumacher | Mercedes | +54 tours |
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